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CCB
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Professorships
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AC
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Clever
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Research - Clever
Projects
double cages, each consisting of a pair of catenated [Pd 2 L 4 ] lantern-shaped helicates ( Frank CEJ 2016 ; Han CSR 2014 ). In contrast to monomeric cages, featuring one large cavity to bind guest molecules [...] show pronounced flipping motion and allow guest binding in an adaptive manner ( Löffler Chem. Sci. 2016 ). In a related study, we showed that the spinning of rotors pointing inside the cage cavity are modulated [...] modulated by their electronic push-pull character and the presence of guests ( Krick Chem. Commun. 2016 ). Figure 3: Cages with pronounced endohedral dynamics, modulated by guest binding: a) flipping of …