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Experimental Splitting of Hydrogen Sulfide by Halogens for Application in Reaction Cycles
the yield than at t = 3–9 s examined previously. The differ- ence in yield (DYHBr) between 1.5 s and 3 s is between 4 % and 9 % for the individual series of measurements, for t = 3–9 s it is DYHBr = 1–4 % [...] disso- ciates in water forming acidic products as in Eq. (9) [28] and will thus interfere with the pH based HCl analysis.
Cl2 þH2OÐ HClþHOCl (9)
To prevent this from happening, KI is also added to the distilled [...] of H2S bromination in stationary state experiments; t = 9 s, TR = 450 C.
Figure 5. HBr yields of the H2S bromination parameter study; t = 1.5–9 s, uBr2 = 10 Mol %, TR = 450 C (¢), 500 C (), 550 C (x), …
